某磷化工产业聚集区周边农田土壤污染调查及成因分析研究

Investigation and Cause Analysis of Soil Pollution in Farmland Surrounding aPhosphorus Chemical Industry Cluster Area

  • 摘要: 以四川省某磷化工产业聚集区周边农田为例,对农田土壤中5项重金属砷、汞、镉、铅、锌进行调查,利用单因素污染指数法和内梅罗综合评价指数法对重金属的污染程度进行评价,结合Kriging插值法,分析了研究区重金属污染物的分布情况,同时运用相关系数和主成分分析对污染物来源进行分析。结果表明,农田土壤中砷、汞、镉、铅、锌的最大值分别为94.2 mg/kg、6.35 mg/kg、27.6 mg/kg、327 mg/kg、5690 mg/kg,均超国家风险筛选值和四川省土壤元素背景值。单因素污染指数均值表现为镉(2.82)>锌(0.81)>汞(0.48)>铅(0.28)>砷(0.27),5种重金属的污染程度均在研究区农田东北角的污水集蓄池附近最高,其中砷、汞、铅、锌的超标点位集中于东北角,镉的污染几乎遍布于整个研究区内。各重金属的变异系数均>100%,属于强变异程度。相关性分析和主成分分析结果显示,5种重金属两两之间均呈现极显著正相关性,工业活动和农业种植是研究区土壤重金属污染的主要原因。

     

    Abstract: Taking the surrounding farmland of a phosphorus chemical industry cluster in Sichuan Province as an example, a survey on As, Hg, Cd, Pb, and Zn in farmland soil was conducted. The pollution level of heavy metals was appraised making use of single factor index evaluation method and Nemerow pollution index evaluation method. Combined with the method of the ordinary kriging interpolation, the distribution condition of heavy metal pollutants in the study area was analyzed, and the sources of pollutants were analyzed using correlation coefficient and principal component analysis. The results showed that the maximum values of As, Hg, Cd, Pb, and Zn in farmland soil were 94.2 mg/kg, 6.35 mg/kg, 27.6 mg/kg, 327 mg/kg, and 5690 mg/kg, respectively, all exceeding the national risk screening values and the background values of soil elements in Sichuan Province. The average single factor pollution index showed Cd(2.82)>Zn(0.81)>Hg(0.48)>Pb(0.28)>As(0.27). The pollution levels of the five heavy metals were highest near the sewage collection tank in the northeast corner of the farmland in the study area, with As, Hg, Pb, and Zn exceeding the standard concentrated in the northeast corner, and Cd pollution almost spreading throughout the entire study area. The coefficient of variation of each heavy metal was greater than 100%, indicating a strong degree of variation. The results of relevance analysis and primary component analysis showed that there was a highly significant positive correlation between each pair of the five heavy metals, and industrial activities and agricultural planting were the main causes of soil heavy metal pollution in the study area.

     

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