云南某冰川侵蚀区域土壤高背景值成因及农作物重金属累积规律探究

Research on the Causes of High Soil Background Value and the Accumulationof Heavy Metals in Crops in a Glacier Eroded Area in Yunnan

  • 摘要: 对采自云南某冰川侵蚀区域的8个岩石样品,10个土壤剖面样品(100cm),75个点位的土壤表层样品,66个农作物样品,利用酸溶法和ICP-MS测定土壤中Cu,Zn,Ni,Pb,Cr,Cd,As和Hg的含量。结果表明: 调查区域玄武岩中的铬、镍和铜含量明显高于灰岩,调查区域范围内土壤超过风险筛选值的因子为铬、镍、砷、铜、镉,其中铬的占比为50%~100%,镍的占比为33%~93.1%,铜的占比为13.64%~93.1%,镉的占比为3.03%~10.34%;超过风险管制值的因子为铬和砷,占比为6.9%、3.03%。除镉和砷的有效态含量占总量的百分比较高之外,其余重金属有效态含量占总量的百分比均很低,铬有效态低于检出限,可能由于铬以不溶态存在于未风化的玄武岩矿物中。采集的59个农产品可食部分砷、铅、汞、镉、铬、锌、铜、镍均未超过对应标准限量值。

     

    Abstract: The content of Cu, Zn, Ni, Pb, Cr, Cd, As and Hg in 8 rock samples, 10 soil profile samples (100cm), 65 soil surface samples and 59 crop samples collected from a glacial-eroded area in Yunnan was determined by acid dissolution and ICP-MS. The results showed that the content of chromium, nickel and copper in basalt in the investigated area was significantly higher than that in limestone, and the metals exceeding the risk screening value of soil in the investigated area were chromium, nickel, copper and cadmium, among which the proportion of chromium was 50%~100%, nickel was 33%~93.1%, copper was 13.64%~93.1%, and cadmium was 3.03%~10.34%. The elements exceeding the risk control value were chromium and arsenic, accounting for 6.9% and 3.03%. Except for the high percentage of cadmium and arsenic in the total amount, the other heavy metals in the total amount of available state content were very low, and the effective state of chromium is lower than the detection limit, which may be due to the insoluble state of chromium in unweathered basalt minerals. The edible parts of arsenic, lead, mercury, cadmium, chromium, zinc, copper and nickel of 59 agricultural products collected did not exceed the corresponding standard limit values.

     

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