燃煤烟气脱汞处理技术
The Removal Technology of Mercury from the Flue Gas of Fired Coal
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摘要: 论述了燃煤烟气中汞的来源、存在形态、危害和脱除效率,综述了除尘装置、选择性催化还原(SCR)脱硝装置、脱硫装置对脱汞效率的作用,固体氧化物催化剂、卤素添加剂对单质汞的催化氧化的影响,探讨了单质汞催化氧化剂类型和脱硫中汞被还原的技术研究难点。燃煤电厂的监测数据表明脱汞中的重点问题有:如何提高SCR催化剂催化氧化单质汞的氧化效率,如何改进催化剂的抗硫性及稳定性,设备防腐蚀问题,如何改善湿法脱硫系统吸收效率以及吸收溶液中的汞沉淀分离技术:这些都是燃煤烟气汞污染控制技术的重点研究内容。Abstract: The sources,forms,damages and removal efficiency of mercury in fired coal flue gas were introduced.The roles of dust removal unit and selected redox denitration equipment and desulfurizing installation on mercury removal efficiency were analyzed. The impacts of solid oxide catalyst and halogen additives on the catalytic oxidation of elemental mercury were analyzed as well to study the technological difficulties of the types of the catalytic oxidation of elemental mercury and deacidizing mercury in the process of desulfurization. The key issues of removing mercury for a fired coal power plant based on the monitoring data were how to increase the oxidation efficiency of elemental mercury by selected redox denitration,how to improve the sulfur-proof and stability of the catalyst to protect the equipment from corrosion,and how to promote the absorbing efficiency of wet desulfurization unit and develop the separation technology of mercury sediments of the absorbing solution.
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