模拟自然因素下固化后河湖底泥中Cr和Pb的释放规律

Simulation of Release of Cr and Pb from Solidified Sediment of River and Lake under Nature Conditions

  • 摘要: 利用土柱试验模拟自然环境因素下固化/稳定化后的试验余土中铬和铅离子的释放规律。结果表明:试验余土中Cr、Pb的总含量相对较高,故以二者为研究对象。随着试验时长的推移,铬离子在不同试验条件下的阶段浸出率几乎不受自然因素的影响,同时铬离子累积浸出率在试验30d后处于平稳状态;而铅离子在不同试验条件下的阶段浸出率也几乎不受自然因素的影响,但是铅离子累积浸出率一直随着时长的推移而增加,直至90d后处于平稳状态。由此可见在相同的自然条件下,河湖底泥中的铬离子优先浸出且达到动态平衡。

     

    Abstract: Soil column tests were used to simulate the release of chromium and lead ions from the solidified/stabilized residual soil in nature conditions. Test conditions involved temperature,rainfall,rainfall pH value and light intensity. The duration of the test was 110 days. Every 10 days,a simulated rainfall test was carried out and the samples were taken. The soil samples and leachate samples were taken at each time,and the contents of heavy metals in the leachate and overflow were measured and analyzed. The results showed that relatively high total content of Cr and Pb in the residual soil. With the passage of the test time,the leaching rate of chromium ion was almost unaffected by natural factors under different test conditions,and the cumulative leaching rate of chromium ion was stable after 30 days of the test; and the leaching rate of lead ion was also in a stable state. Under different experimental conditions,the leaching rate at different stages was unaffected by natural factors,but the cumulative leaching rate of lead ion increased until 90 days. Therefore,chromium ions of sediments of rivers and lakes were leached and dynamic equilibrium preferentially,in same nature conditions.

     

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